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http://hdl.handle.net/11701/2238
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Поле DC | Значение | Язык |
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dc.contributor.author | Davidovich, Pavel B. | - |
dc.contributor.author | Gurzhiy, Vladislav V. | - |
dc.contributor.author | Sanina, N.A. | - |
dc.contributor.author | Shchukarev, A.V. | - |
dc.contributor.author | Garabadzhiu, A.V. | - |
dc.contributor.author | Belyaev, A.N. | - |
dc.date.accessioned | 2016-05-06T11:50:47Z | - |
dc.date.available | 2016-05-06T11:50:47Z | - |
dc.date.issued | 2015-04 | - |
dc.identifier.citation | doi:10.1016/j.poly.2015.02.009 | en_GB |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/11701/2238 | - |
dc.description.abstract | New dinitrosyl iron complexes of binuclear structure [Fe2(μ-SCHMe2)2(NO)4] and [Fe2(μ-SCHPh2)2(NO)4] were first synthesized employing new method from Fe(CO)5, corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied. | en_GB |
dc.description.sponsorship | The work has been supported by the Ministry of Education and Science of the Russian Federation (State Contract 14.B25.310013) and the Program of the Presidium of RAS “Fundamental sciences for medicine”. XRD study has been prepared at the X-ray Diffraction Centre of Saint-Petersburg State University. NMR studies were performed by S. Smirnov at the Centre for Magnetic Resonance of Saint-Petersburg State University | en_GB |
dc.language.iso | en | en_GB |
dc.publisher | Elsevier | en_GB |
dc.relation.ispartofseries | Polyhedron;V. 90. | - |
dc.subject | Crystal structure | en_GB |
dc.subject | Thiolate ligands | en_GB |
dc.subject | Dinitrosyl iron complex | en_GB |
dc.subject | Nitric oxide donor | en_GB |
dc.subject | DFT calculations | en_GB |
dc.title | Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe2(μ-SCHR2)2(NO)4], R = Me, Ph | en_GB |
dc.type | Article | en_GB |
Располагается в коллекциях: | Articles |
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Файл | Описание | Размер | Формат | |
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2015_Davidovich_Polyhedron_Fe.pdf | 651,31 kB | Adobe PDF | Просмотреть/Открыть |
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