Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на этот ресурс: http://hdl.handle.net/11701/6015
Полная запись метаданных
Поле DCЗначениеЯзык
dc.contributor.authorMatveeva, Svetlana G.-
dc.contributor.authorPozdnyakov, Ivan P.-
dc.contributor.authorGrivin, Vjacheslav P.-
dc.contributor.authorPlyusnin, Victor F.-
dc.contributor.authorMereshchenko, Andrey S.-
dc.contributor.authorMelnikov, Alexey A.-
dc.contributor.authorChekalin, Sergey V.-
dc.contributor.authorGlebov, Evgeni M.-
dc.date.accessioned2017-03-13T08:49:20Z-
dc.date.available2017-03-13T08:49:20Z-
dc.date.issued2016-04-06-
dc.identifier.citationJ. Photochem. Photobiol. A: Chem, 2016, 325, 13-21.en_GB
dc.identifier.urihttp://hdl.handle.net/11701/6015-
dc.description.abstractPhotosolvation of hexachloroplatinate(IV) in acetonitrile with the formation of the PtIVCl5(CH3CN)− complex was studied in the time range from hundreds of femtoseconds to seconds. The primary Pt(III) intermediate was recorded and interpreted as the primary Adamson radical pair [PtIIICl52‐(C4v)⋯Clradical dot], which then accepts an electron from a solvent molecule. Two successive Pt(III) intermediates recorded in time range from microseconds to tens of milliseconds were interpreted as PtIIICl52−(C4V) and PtIIICl4− complexes. PtIIICl4− was proposed to be a chain carrier in the chain photosolvation process. Dependencies of quantum yield of photosolvation on the initial complex concentration and excited light intensity were fitted in the framework of the proposed chain mechanism. Rate constants of the reactions of intermediates were determined.en_GB
dc.description.sponsorshipРФФИ № 15-13-10012en_GB
dc.language.isoenen_GB
dc.publisherElsevieren_GB
dc.titlePrimary photochemical processes for PtCl62− complex in acetonitrile solutionsen_GB
dc.typeArticleen_GB
Располагается в коллекциях:Articles

Файлы этого ресурса:
Файл Описание РазмерФормат 
3_JPPA2016_PtCl62-_CH3CN.pdf1,44 MBAdobe PDFПросмотреть/Открыть


Все ресурсы в архиве электронных ресурсов защищены авторским правом, все права сохранены.