Архив открытого доступаСанкт-Петербургского государственного университета
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http://hdl.handle.net/11701/2242Полная запись метаданных
| Поле DC | Значение | Язык |
|---|---|---|
| dc.contributor.author | Gurzhiy, Vladislav V. | - |
| dc.contributor.author | Tyumentseva, Olga S. | - |
| dc.contributor.author | Krivovichev, Sergey V. | - |
| dc.contributor.author | Tananaev, Ivan G. | - |
| dc.date.accessioned | 2016-05-06T12:40:31Z | - |
| dc.date.available | 2016-05-06T12:40:31Z | - |
| dc.date.issued | 2015-05 | - |
| dc.identifier.issn | 1521-3749 | - |
| dc.identifier.other | 10.1002/zaac.201500208 | - |
| dc.identifier.uri | http://hdl.handle.net/11701/2242 | - |
| dc.description.abstract | The hybrid organic-inorganic uranyl selenate, [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)] (I), was prepared by isothermal evaporation from aqueous solutions. The crystal structure of I [orthorhombic, Pnma, a = 15.386(3), b = 10.771(2), c = 13.239(3) Å, V = 2194.0(7) Å3, Z = 4, R1 = 0.042] is based upon complex 15-crown-5-ether-uranyl-selenate polymeric units consisting of uranyl selenate chains decorated by [K@(15-crown-5)]+ complexes via strong ionic K+–O bonds. The 1D hybrid units are packed in a parquetted-like fashion and connected to each other by hydrogen bonds and residual van der Waals interactions. | en_GB |
| dc.description.sponsorship | This work was supported by St. Petersburg State University (grant 3.38.136.2014) and President of Russian Federation grant for young scientists (no. MK-1737.2014.5 to V. V. G.). The XRD studies have been performed at the X-ray Diffraction Centre of St. Petersburg State University. | en_GB |
| dc.language.iso | en | en_GB |
| dc.publisher | Wiley | en_GB |
| dc.relation.ispartofseries | Zeitschrift für anorganische und allgemeine Chemie;V. 641. Issue 6 | - |
| dc.subject | Uranyl selenate | en_GB |
| dc.subject | Crown ether | en_GB |
| dc.subject | Potassium | en_GB |
| dc.subject | Topology | en_GB |
| dc.subject | Crystal structure | en_GB |
| dc.title | Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization | en_GB |
| dc.type | Article | en_GB |
| Располагается в коллекциях: | Articles | |
Файлы этого ресурса:
| Файл | Описание | Размер | Формат | |
|---|---|---|---|---|
| 2015_ZAAC_KUSeCr.pdf | 442,79 kB | Adobe PDF | Просмотреть/Открыть |
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