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http://hdl.handle.net/11701/2107
Полная запись метаданных
Поле DC | Значение | Язык |
---|---|---|
dc.contributor.author | Smirnov, Andrey S. | - |
dc.contributor.author | Butukhanova, Ekaterina S. | - |
dc.contributor.author | Bokach, Nadezhda A. | - |
dc.contributor.author | Starova, Galina L. | - |
dc.contributor.author | Gurzhiy, Vladislav V. | - |
dc.contributor.author | Kukushkin, Vadim Yu. | - |
dc.date.accessioned | 2016-04-15T17:15:44Z | - |
dc.date.available | 2016-04-15T17:15:44Z | - |
dc.date.issued | 2015 | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.uri | http://hdl.handle.net/11701/2107 | - |
dc.description.abstract | ZnII-activated cyanamides NCNR2 (R2 = Me2, Et2, C5H10, C4H8O, Ph2) react with the acyclic N-alkyl ketonitrones Ph2C=N+(O–)R’ (R’ = Me, CH2Ph) and N-aryl ketonitrones (R’ = Ph, p-BrC6H4, p-EtC6H4) under mild conditions. Uncomplexed 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles (6 examples; 49–82%) were obtained in zinc(II)-involving cycloaddition of the N-alkyl ketonitrones to the cyanamide substrates; these 2,3-dihydro-1,2,4-oxadiazoles undergo ring-opening giving carbamoylamidines and methylidenureas. The N-aryl ketonitrones react with ZnII-activated cyanamides giving the open-chain systems, viz. carbamoylamidines, N'-(2-(diphenylmethylidene)amino)-phenyl-N,N-carbamimidic acids, and methylidenureas, which are presumably formed via the cycloaddition route followed by the N–O cleavage induced by the acceptor character of the aryl groups. | en_GB |
dc.language.iso | en | en_GB |
dc.publisher | RSC | en_GB |
dc.relation.ispartofseries | New Journal of Chemistry;39 | - |
dc.subject | 2,3-Dihydro-1,2,4-oxadiazoles | en_GB |
dc.title | Facile zinc(II)-mediated generation of 5-amino substituted 2,3-dihydro-1,2,4-oxadiazoles and their further ZnII-catalyzed and O2-involving transformations, New J. Chem., 39 (2015) 9330–9344, DOI: 10.1039/C5NJ02061A | en_GB |
dc.type | Article | en_GB |
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