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http://hdl.handle.net/11701/1983
Полная запись метаданных
Поле DC | Значение | Язык |
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dc.contributor.author | Mereshchenko, Andrey S. | - |
dc.contributor.author | Olshin, Pavel K. | - |
dc.contributor.author | Karimov, Artur M. | - |
dc.contributor.author | Skripkin, Mikhail Yu. | - |
dc.contributor.author | Burkov, Kim A. | - |
dc.contributor.author | Tveryanovich, Yury S. | - |
dc.contributor.author | Tarnovsky, Alexander N. | - |
dc.date.accessioned | 2016-04-08T09:09:43Z | - |
dc.date.available | 2016-04-08T09:09:43Z | - |
dc.date.issued | 2014-11-05 | - |
dc.identifier.citation | Mereshchenko, A. S.; Olshin, P.K.; Karimov, A.M.; Skripkin, M. Yu.; Burkov, K.A.; Tveryanovich, Yu. S.; Tarnovsky, A. N. Chem. Phys. Lett., 2014, 615, 105-110. | en_GB |
dc.identifier.uri | http://hdl.handle.net/11701/1983 | - |
dc.description.abstract | Photochemistry of [Cu(MeCN)(3)Cl](+), [Cu(MeCN)Cl-3](-), and [CuCl4](2-) copper(II) chlorocomplexes in acetonitrile solution is studied by means of the combination of the steady-state photolysis and ultrafast transient absorption methods. The main relaxation pathways of the initially excited ligand-to-metal charge transfer states are internal conversion to the ground state, ionic dissociation without (photo)reduction of copper(II), and radical dissociation with (photo)reduction of copper(II). The copper(II)-to-copper(I) photoreduction quantum yields obtained from steady-state photolysis correlate with ultrafast spectroscopy data. The presence of oxygen does not affect the photoreduction quantum yields, which do not exceed 7% for the complexes studied and decrease in the series: [Cu(MeCN)(3)Cl](+) > [Cu(MeCN)Cl-3](-) > [CuCl4](2-). | en_GB |
dc.language.iso | en | en_GB |
dc.publisher | CHEMICAL PHYSICS LETTERS | en_GB |
dc.title | Photochemistry of copper(II) chlorocomplexes in acetonitrile: Trapping the ligand-to-metal charge transfer excited state relaxations pathways | en_GB |
dc.type | Article | en_GB |
Располагается в коллекциях: | Articles |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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CPL2014_Photochemistry of copper(II) chlorocomplexes in acetonitrile.pdf | 833,43 kB | Adobe PDF | Просмотреть/Открыть |
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