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http://hdl.handle.net/11701/1965
Полная запись метаданных
Поле DC | Значение | Язык |
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dc.contributor.author | Köckerling Martin, Peppel Tim | - |
dc.contributor.author | Thiele Philipp, Verevkin Sergey P. | - |
dc.contributor.author | Emel’yanenko Vladimir N., Samarov Artemiy A. | - |
dc.contributor.author | Ruth Wolfgang | - |
dc.date.accessioned | 2016-04-08T07:21:34Z | - |
dc.date.available | 2016-04-08T07:21:34Z | - |
dc.date.issued | 2015 | - |
dc.identifier.issn | 14341948 | - |
dc.identifier.uri | http://hdl.handle.net/11701/1965 | - |
dc.description.abstract | It was a big surprise to see crystals of an ionic liquid (IL) forming by sublimation at room temperature. ILs are gen- erally accepted to have negligible vapour pressures at ele- vated temperatures, making their sublimation or distillation very difficult. ILs that sublime easily contain silylimid- azolium-based cations. In order to establish the details of the unusual behaviour of this subclass of ILs, a combined spec- troscopic, X-ray crystallographic, physicochemical and theo- retical characterization was performed. The results are com- pared with those of other easily vaporizable compounds, like ammonium chloride and naphthalene. The single-crystal X- ray structure analysis of one of these compounds, N-methyl- N?-dimethyl(phenyl)silylimidazolium chloride (monoclinic, C2/c), clearly shows the existence of isolated ions, demon- strating that the compound is an ionic liquid. | en_GB |
dc.language.iso | en | en_GB |
dc.relation.ispartofseries | European Journal of Inorganic Chemistry;24 | - |
dc.subject | Ionic liquids | en_GB |
dc.subject | Silylimidazoles | en_GB |
dc.subject | Boiling point | en_GB |
dc.subject | Solid-state structures | en_GB |
dc.subject | Thermochemistry | en_GB |
dc.subject | Sublimation | en_GB |
dc.title | Easily Vaporizable Ionic Liquids – No Contradiction! | en_GB |
dc.type | Article | en_GB |
Располагается в коллекциях: | Articles |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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Köckerling et al. - 2015 - Easily Vaporizable Ionic Liquids - No Contradiction!.pdf | 5,06 MB | Adobe PDF | Просмотреть/Открыть |
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