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http://hdl.handle.net/11701/10355
Полная запись метаданных
Поле DC | Значение | Язык |
---|---|---|
dc.contributor.author | Siidra, Oleg I | - |
dc.contributor.author | Nazarchuk, Evgeny V | - |
dc.contributor.author | Charkin, Dmitry O | - |
dc.contributor.author | Chukanov, Nikita V | - |
dc.contributor.author | Depmeier, Wulf | - |
dc.contributor.author | Bocharov, Sergey N | - |
dc.contributor.author | Sharikov, Mikhail I | - |
dc.date.accessioned | 2018-07-01T08:25:54Z | - |
dc.date.available | 2018-07-01T08:25:54Z | - |
dc.date.issued | 2018-04-03 | - |
dc.identifier | 10.3390/nano8040216 | - |
dc.identifier.issn | 10.3390/nano8040216 | - |
dc.identifier.uri | http://hdl.handle.net/11701/10355 | - |
dc.description.abstract | The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH⁺)₇[(UO₂)₆(SO₄)10](H₂O)3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO₂)₆(SO₄)10]8- nanotubules templated by protonated N-phenylglycine (C₆H₅NH₂CH₂COOH)⁺. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO₄ tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules. | en_GB |
dc.description.sponsorship | This work was financially supported by the Russian Science Foundation through the grant 16-17-10085. Technical support by the SPbSU X-ray Diffraction, Thermal Analysis and Calorimetry, Microscopy and Microanalysis Resource Centers is gratefully acknowledged. | en_GB |
dc.language.iso | en | en_GB |
dc.publisher | MDPI | en_GB |
dc.subject | nanostructured materials | en_GB |
dc.subject | nanotubes | en_GB |
dc.subject | actinide materials | en_GB |
dc.subject | organically templated compounds | en_GB |
dc.title | Uranyl Sulfate Nanotubules Templated by N-phenylglycine | en_GB |
Располагается в коллекциях: | Articles |
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Файл | Описание | Размер | Формат | |
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nanomaterials_1.compressed.pdf | Main article | 647,21 kB | Adobe PDF | Просмотреть/Открыть |
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